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K72

Publication of the Department of Nanometrology in Materials

Date: 14.11.2020

Congratulations to prof. Andrzej Sikora and other co-authors of the publication of the work „Comparison of physicochemical properties of carboxylic and phosphonic acid self-assembled monolayers created on the Ti-6Al-4V substrate” in the renowned Materials (IF=3.057). We wish everyone further scientific successes.

Comparison of physicochemical properties of carboxylic and phosphonic acid self-assembled monolayers created on the Ti-6Al-4V substrate

Michał Cichomski, Milena Prowizor, D.A. Kowalczyk, Andrzej Sikora, Damian Batory, Mariusz Dudek

This study compared the tribological properties in nano- and millinewton load ranges of Ti-6Al-4V surfaces that were modified using self-assembled monolayers (SAMs) of carboxylic and phosphonic acids. The effectiveness of the creation of SAMs with the use of the liquid phase deposition (LPD) technique was monitored by the contact angle measurement, the surface free energy (SFE) calculation, X-ray photoelectron spectroscopy (XPS), and Fourier-transform infrared spectroscopy (FTIR) measurements. The obtained results indicated that more stable and well-ordered layers, which were characterized by the lowest values of the coefficient of friction, adhesion, and wear rate, were obtained using phosphonic acid as a surface modifier. Based on the obtained results, it was found that the Ti-6Al-4V alloy modified by phosphonic acid would be the most advantageous for practical applications, especially in micro- and nanoelectromechanical systems (MEMS/NEMS).

doi:10.3390/ma13225137

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